四川农业大学学报 ›› 1995, Vol. 13 ›› Issue (02): 242-246,225.doi: 10.16036/j.issn.1000-2650.1995.02.027

• 研究论文 • 上一篇    下一篇

毒物砷的测定及价态分析方法

陈柏林1, 谢君2   

  1. 1. 四川农业大学动物营养研究所, 雅安市 625014;
    2. 四川农业大学动物营养工学院, 雅安市 625014
  • 收稿日期:1994-10-18 出版日期:1995-06-30 发布日期:2017-04-22

TOXIC ARSENIC DETERMINATION AND ITS VALENT STATE ANALYSIS

Chen Bolin1, Xie Jun2   

  1. College of Animal Science and Technology, Sichuan Agricultutal University, Yaan, Sichuan, China 625014
  • Received:1994-10-18 Online:1995-06-30 Published:2017-04-22

摘要: 本文比较系统地介绍了毒物砷的测定方法,尤其是对当前应用最广的砷斑法,银盐法的特点,灵敏度,线性范围作了讨论,从而推荐了一种更好的方法:新银盐测砷法。在砷的价态分析中,主要介绍了萃取法,巯基棉富集法,离子交换法,砷化氢挥发法的反应条件,试剂用量,介质酸度等,对常用方法中干扰的消除也作了介绍。

关键词: 砷, 测定, 价态分析

Abstract: The paper introduces some methods for the determination of toxic Arsenic and especially discusses the characteristics, sensitivity, linear range of "Gutzeit" and "Silver Salt Photometry" methods which are now widely used. Consequently, a better method. or "a New Silver Salt Photometry," was recommended. In Arsenic valent state analysis, it mainly introduced "extraction method", "enriched method by sulfhydryl cotton fiber","ionic exchange method" and "hydride generation spectrophotometric method", and their analysis conditions, reageants quantities, medium pH, etc. They are very useful I in practice. The paper also recommends some means about elimination interferences of a few elements in metioned methods.

Key words: ARSENIS DETTERMINATION, VALENT ANALYSIS

中图分类号: 

  • O613.63